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A photo-induced electron transfer study of an organic dye anchored on the surfaces of TiO2 nanotubes and nanoparticles

发表时间:2019-03-11
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论文类型:
期刊论文
第一作者:
Hu, Shen
通讯作者:
Liu, M; Song, CS (reprint author), Dalian Univ Technol, Sch Chem Engn, PSU DUT Joint Ctr Energy Res, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
合写作者:
Liu, Min,Guo, Xinwen,Kuang, Zhichong,Li, Keyan,Song, Chunshan,Zhang, Guoliang
发表时间:
2018-06-01
发表刊物:
JOURNAL OF SOLID STATE CHEMISTRY
收录刊物:
SCIE、EI
文献类型:
J
卷号:
262
页面范围:
237-243
ISSN号:
0022-4596
关键字:
MOFs; NH2-MIL-125; Morphology
摘要:
Titanium based MOF materials NH2-MIL-125 was synthesized through solvothermal method. By increasing the concentration of the reactants, the morphology of NH2-MIL-125 can be controlled from circular plate to special polyhedron. Meanwhile, the polyhedron can be modulated from octahedron to rhombic dodecahedron through changing the titanium ester of the reactants from tetraethyl titanate to tetrabutyl titanate. This is the first time to obtain NH2-MIL-125 with rhombic dodecahedron morphology. The test of acetic acid as additive on morphology changes shows that the adsorption of additives on special facets shows a more significant impact on the morphology formation. The morphology control of NH2-MIL-125 based on the modulation of the type of titanium ester, reactants concentration, and the added acetic acid concentration were detailed exhibited and explained.
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