甲烷在Cr改性Pd/Al2O3催化剂上的催化燃烧性能
Release time:2022-10-16
Hits:
First Author:苑兴洲
Correspondence Author:Richard,陈恒,zhangyongchun
Date of Publication:2022-10-06
Journal:化工进展
Document Type:J
Issue:12
Page Number:3258-3262,3282
ISSN No.:1000-6613
Abstract:The effects of CrAl carrier preparation process and Pd loading methods on the catalytic activity of Cr modified Pd/Al2O3 catalyst for low concentration methane combustion were investigated,and the influence of Ce addition on the high-temperature stability of catalyst was also tested. X-ray diffraction and temperature programmed reduction were used to characterize the structure and redox ability of catalysts. The I-CrAl carrier prepared by impregnation had high specific surface area,and the pores were not blocked. Reduction treatment in the process of Pd loading significantly improved the activity of catalysts. Temperature-programmed reduction with hydrogen verified that the reduction process improved the catalyst reduction ability. Addition of Ce enhanced catalyst stability by resisting sintering of Al2O3 at high temperature.
Note:新增回溯数据
Translation or Not:no
Next One:甲醇和乙醇在二氧化碳中的竞争吸附