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The role of copper species on Cu/gamma-Al2O3 catalysts for NH3-SCO reaction
Release time:2019-03-09 Hits:
Indexed by: 期刊论文
First Author: Liang, Chunxia
Correspondence Author: Li, XY (reprint author), Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn, Dalian 116024, Peoples R China.
Co-author: Li, Xinyong,Qu, Zhenping,Tade, Moses,Liu, Shaomin
Date of Publication: 2012-02-01
Journal: APPLIED SURFACE SCIENCE
Included Journals: EI、SCIE
Document Type: J
Volume: 258
Issue: 8
Page Number: 3738-3743
ISSN No.: 0169-4332
Key Words: NH3-SCO; Cu/gamma-Al2O3; Dispersion; Copper species
Abstract: UV-vis spectra, XRD, H-2-TPR, TEM and ESR were used to characterize a series of Cu/gamma-Al2O3 catalysts, which were prepared by incipient wetness impregnation using copper nitrate, copper acetate or copper sulfate as precursors, to study the role of Cu species on Cu/gamma-Al2O3 catalysts for NH3-SCO reaction. It was found that the mixture of CuO phase and CuAl2O4 phase formed on various Cu/gamma-Al2O3 catalysts, and the Cu species and dispersion had significant influence on the Cu/gamma-Al2O3 activity. Highly dispersed CuO phase on the support would be related with its high activity for the NH3-SCO reaction. (C) 2011 Elsevier B. V. All rights reserved.
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