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The NiAl mixed oxides: The relation between basicity and SO2 removal capacity

发表时间:2019-03-09
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论文类型:
期刊论文
第一作者:
Zhao, Ling
通讯作者:
Li, XY (reprint author), Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn, Dalian 116024, Peoples R China.
合写作者:
Li, Xinyong,Qu, Zhenping,Zhao, Qidong,Liu, Shaomin,Hu, Xijun
发表时间:
2011-07-29
发表刊物:
SEPARATION AND PURIFICATION TECHNOLOGY
收录刊物:
SCIE、EI
文献类型:
J
卷号:
80
期号:
2
页面范围:
345-350
ISSN号:
1383-5866
关键字:
SO2 removal; NiAl mixed oxides; Adsorption
摘要:
A series of NiAl mixed oxides derived from hydrotalcite-like compounds were prepared by a urea hydrolysis method, and characterized by TGA, XRD, SEM, CO2-TPD, N-2 adsorption/desorption and XPS techniques. The SO2 adsorption capacity of the materials correlated closely with their basicity and active oxygen species on the surface, as estimated by a volumetric method. The NiAl mixed oxide with the optimal Ni/Al molar ratio of 3 showed the best performance of SO2 adsorption. Moreover, its adsorption equilibrium of a type I isotherm and pore opening in the quasi-micropore region significantly improve the adsorption performance for low-concentration SO2. (C) 2011 Elsevier B.V. All rights reserved.
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