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Enhanced performance of superhydrophobic polypropylene membrane with modified antifouling surface for high salinity water treatment
Release time:2019-11-07 Hits:
Indexed by: 期刊论文
First Author: Wang, Yingqi
Correspondence Author: Jiang, XB (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Engn Lab Petrochem Energy Efficient Separat Techn, Sch Chem Engn, Dalian 116024, Peoples R China.
Co-author: He, Gaohong,Shao, Yushan,Zhang, Daishuang,Ruan, Xuehua,Xiao, Wu,Li, Xiangcun,Wu, Xuemei,Jiang, Xiaobin
Date of Publication: 2019-05-01
Journal: SEPARATION AND PURIFICATION TECHNOLOGY
Included Journals: EI、SCIE、CPCI-S
Document Type: J
Volume: 214
Issue: ,SI
Page Number: 11-20
ISSN No.: 1383-5866
Key Words: Membrane distillation; Superhydrophobic membrane; Antifouling; Nucleation; Water treatment
Abstract: In this work, the superhydrophobic polypropylene (PP) composite membranes with modified surface were successfully fabricated by loading the SiO2 nanoparticles and attaching low surface energy 1H,1H,2H,2H-perfluorodecyltriethoxysilane. The impact of deposited nanoparticle size on the surface roughness, heterogeneous nucleation barrier and critical nucleus size versus the loaded nanoparticle size (d(nuclear)(*)/d) was simulated by the model combining the surface roughness and superhydrophobility with the critical nucleation energy. The optimized loaded nanoparticles size maintained the proper roughness and d(nuclear)(*)/d to ensure the desired performance of antifouling. The improved superhydrophobic surface enhanced the anti-wetting ability of the membrane for vacuum membrane distillation (VMD) purpose. The resulting modified membrane possessed good anti wetting ability and stable anti-fouling performance during long-term continuous and batch operation of VMD treating high salinity water system. The fouling rate of the fabricated membrane was decreased to 20% of the one of the original membrane under 15 wt% high salinity feed condition.
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