Indexed by:
期刊论文
First Author:
Zhao, Rui
Correspondence Author:
He, GH (reprint author), Dalian Univ Technol, R&D Ctr Membrane Sci & Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
Co-author:
Li, Xiangcun,Zhang, Xiaodan,Xu, Jiping,He, Gaohong,Dong, Chunxu,Jiang, Xiaobin
Date of Publication:
2014-10-01
Journal:
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
Included Journals:
SCIE、EI
Document Type:
J
Volume:
35
Issue:
10
Page Number:
1369-1377
ISSN No.:
0193-2691
Key Words:
aggregation mechanism; emulsion liquid membrane; heterojunction;
surfactant adsorption; zinc oxide
Abstract:
We have investigated the formation and evolution of zinc oxalate particles in internal aqueous droplets and their effects of emulsion interface properties. The formation of particles follows an aggregation-controlled mechanism that depends on the size of droplets and surfactant. The size of droplets determines the final shape of the particles by affecting the supersaturation ratio to form rod-like and sheet-like particles. The surfactant adsorbed on the particles changes the wettability, leading to the aggregation of the primary particles at the internal water-oil interface. Moreover, the adsorption can cause a higher level of impurity and defects in as-synthesized particles. This effect could be directly employed to fabricate heterojunction rectifier.
Translation or Not:
no
