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新型肼桥联共价三嗪聚合物在二氧化碳捕集和催化转化方面的应用(英文)
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双恶唑啉-苯基稀土金属化合物合成及催化异戊二烯聚合性能研究
氮杂环卡宾铜配合物催化端炔、CO_2和烯丙基氯的羧化偶联反应
Release time:2019-03-11
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Indexed by:
会议论文
First Author:
张文珍
Co-author:
张潇,李文杰,吕小兵
Date of Publication:
2010-10-22
Document Type:
A
Page Number:
1
Key Words:
偶联反应;CO_2;卡宾;铜配合物;氮杂环;过渡金属催化;亲电试剂;烯丙基氯;羧化;亲核试剂;
Abstract:
作为造成全球气候变暖的主要温室气体及储量丰富、廉价易得的可再生性碳资源的CO_2,其催化转化合成有用的有机化合物的研究受到了极大的关注。CO_2可作为亲电试剂与碳亲核试剂进行羧化反应制备有机羧酸或羧酸酯。过渡金属催化的有机硼、有机锌及有机铜等反应活性较低的亲核试剂与CO_2的羧化反
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no