Highly efficient conversion of CO2 to cyclic carbonates with a binary catalyst system in a microreactor: intensification of "electrophile-nucleophile" synergistic effect
Release time:2019-03-12
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First Author:
Li, Ming-Ran
Correspondence Author:
Ren, WM (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China.
Co-author:
Zhang, Ming-Chao,Yue, Tian-Jun,Lu, Xiao-Bing,Ren, Wei-Min
Date of Publication:
2018-01-01
Journal:
RSC ADVANCES
Included Journals:
SCIE
Document Type:
J
Volume:
8
Issue:
68
Page Number:
39182-39186
ISSN No.:
2046-2069
Abstract:
An intensification of the electrophile-nucleophile synergistic effect was achieved in a microreactor for the coupling reaction of CO2 and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparation of cyclic carbonates with an improved reaction rate and a wide substrate scope.
Translation or Not:
no
