Indexed by:
期刊论文
First Author:
Liu, Ye
Correspondence Author:
Lu, XB (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
Co-author:
Ren, Wei-Min,Liu, Jie,Lu, Xiao-Bing
Date of Publication:
2013-10-25
Journal:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Included Journals:
SCIE、EI、PubMed、Scopus
Document Type:
J
Volume:
52
Issue:
44
Page Number:
11594-11598
ISSN No.:
1433-7851
Key Words:
carbon dioxide; cobalt; copolymerization; meso-epoxides; polycarbonates
Abstract:
Unprecedented enantioselectivity and catalytic activity was observed in the asymmetric copolymerization of CO2 with meso-epoxides (including the less reactive cyclopentene oxide) mediated by the dinuclear Co(III) complex (S,S,S,S)-1 under mild conditions. The resultant copolymers possess more than 99 % carbonate linkages and a perfectly isotactic structure.Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Translation or Not:
no
