Indexed by:
期刊论文
First Author:
Wang, Lixiao
Correspondence Author:
Cui, JN (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, 158 Zhongshan Rd, Dalian 116012, Peoples R China.
Co-author:
Wang, Xingyong,Cui, Jingnan,Ren, Weimin,Meng, Nan,Wang, Jingyun,Qian, Xuhong
Date of Publication:
2010-04-21
Journal:
TETRAHEDRON-ASYMMETRY
Included Journals:
SCIE
Document Type:
J
Volume:
21
Issue:
7
Page Number:
825-830
ISSN No.:
0957-4166
Abstract:
A series of trans-5-substauted-acenaphthene-1,2-diols were obtained in 21-72% yield with 97-100% ee by baker's yeast-mediated reduction of the corresponding acenaphthylene-1,2-diones, in the presence of DMSO as a co-solvent and under vigorous agitation The absolute configuration of (-)-trans-5-methoxy-acenaphthene-1,2-diol trans-3b and (-)-trans-5-bromo-acenaphthene-12-diol trans-3c was assigned as (S,S) and (-)-trans-5-thiomorpholin-acenaphthene-1,2-diol trans-3d was established as (R,R) by exciton-coupled circular dichroism. (C) 2010 Elsevier Ltd All rights reserved
Translation or Not:
no
