Indexed by:
期刊论文
First Author:
Tong, Lian Peng
Correspondence Author:
Cui, JN (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China.
Co-author:
Cui, Jing Nan,Ren, Wei Min,Wang, Xing Yong,Qian, Xu Hong
Date of Publication:
2008-10-01
Journal:
CHINESE CHEMICAL LETTERS
Included Journals:
SCIE、ISTIC、Scopus
Document Type:
J
Volume:
19
Issue:
10
Page Number:
1179-1182
ISSN No.:
1001-8417
Key Words:
Bioreduction; Plant enzymes; Acenaphthenequinone; Chiral
hydroxyacenaphthenone
Abstract:
Regio- and enantioselective reduction of substituted acenaphthenequinones were conducted under mild reaction conditions using plant enzymatic systems. A screening of 15 plants allowed the selection of two suitable plants fulfilling enantiocomplementarity. The (+)- and (-)-mono hydroxyacenaphthenones were achieved with high conversion and good enantiomeric purity using peach (Prunus persica (L.) Batsch., conversion 98%, 71% ee) and carrot (Daucus carota L., conversion 95%, 81% ee), respectively. (C) 2008 Jing Nan Cui. Published by Elsevier B. V. on behalf of Chinese Chemical Society. All rights reserved.
Translation or Not:
no
