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Small molecule activation and biomimetic catalysis
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双功能手性Salen型金属配合物分子内协同催化CO<,2>与环氧烷烃的不对称环加成反应
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Asymmetric coupling of CO2 and epoxides catalyzed by multi-chiral cobalt(III) complexes
双功能手性Salen型金属配合物分子内协同催化COlt;,2gt;与环氧烷烃的不对称环加成反应
Release time:2019-03-10
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会议论文
First Author:
张翔
Co-author:
贾银保,吕小兵,孙立成
Date of Publication:
2007-10-01
Document Type:
A
Key Words:
金属配合物;分子内协同催化;环氧烷烃;不对称环加成反应
Abstract:
不对称催化合成是现代有机化学中最为活跃的研究领域之一。产物的构筑。本文论述了基于手性Salen型钻配合物的含手性亲电试剂和亲核试剂的双组分催化剂，成功实现了在室温、低压的温和条件下用外消旋环氧烷烃为原料直接一步合成光学活性环状碳酸酯。
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