Crystalline and Elastomeric Poly(monothiocarbonate)s Prepared from Copolymerization of COS and Achiral Epoxide
发表时间：2019-03-12
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- 论文类型：
- 期刊论文
- 第一作者：
- Ren, Wei-Min
- 通讯作者：
- Ren, WM (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China.
- 合写作者：
- Yue, Tian-Jun,Li, Ming-Ran,Wan, Zhao-Qian,Lu, Xiao-Bing
- 发表时间：
- 2017-01-10
- 发表刊物：
- MACROMOLECULES
- 收录刊物：
- SCIE、EI
- 文献类型：
- J
- 卷号：
- 50
- 期号：
- 1
- 页面范围：
- 63-68
- ISSN号：
- 0024-9297
- 摘要：
- The semicrystalline poly(monothiocarbonate)s were prepared by the copolymerization of carbonyl sulfide (COS) and ethylene oxide, an achiral epoxide, using a bifunctional chromium(III) complex as catalyst. The resultant copolymer, possessing perfectly alternating structure, high molecular weight, and narrow polydispersity, has a melting temperature of 128.2 degrees C, with a melting enthalpy up to 75.44 J/g. Moreover, an ABA triblock copolymer containing the "hard" semicrystalline poly(ethylene monothiocarbonate) (A) and the "soft" amorphous poly(propylene monothiocarbonate) (B) is synthesized by stepwise addition of epoxides. The tensile testing demonstrates the triblock copolymer may have the potential as a thermoplastic elastomer.
- 是否译文：
- 否
