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A simple one pot synthesis of mesoporous silica hosted silver catalyst and its low-temperature CO oxidation

发表时间:2019-03-09
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论文类型:
期刊论文
第一作者:
Qu, Zhenping
通讯作者:
Qu, ZP (reprint author), Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn, MOE, Linggong Rd 2, Dalian 116024, Peoples R China.
合写作者:
Zhang, Xiaodong,Yu, Fangli,Jia, Jingxuan
发表时间:
2014-04-01
发表刊物:
MICROPOROUS AND MESOPOROUS MATERIALS
收录刊物:
SCIE、EI、Scopus
文献类型:
J
卷号:
188
页面范围:
1-7
ISSN号:
1387-1811
关键字:
Ag nanoparticles; CO oxidation; DDA; HMS; One pot synthesis
摘要:
A novel and simple one pot synthesis approach using dodecylamine (DDA) as capping agent and structure director has been employed to synthesize the silica-supported Ag nanoparticles. The catalysts were characterized by XRD, N-2 adsorption-desorption isotherms, TEM and TG-DTA. It was found that the loading and particle size of Ag were strongly related to the surfactant DDA. In addition, the formed local reductive environmental due to the decomposition of DDA during thermal treatment procedure could prevent the aggregation of Ag nanoparticles and be benefit for the formation of uniformly dispersed Ag nanoparticles on the HMS support (1.5-4.5 nm). The excellent catalytic activity for CO oxidation (T-98(CO) = 20 degrees C) demonstrated that the method was effective for synthesizing the highly dispersed nano-silver catalyst (C) 2014 Elsevier Inc. All rights reserved.
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