Selective oxidation of cyclopentene to glutaraldehyde over the WO3/SiO2 catalyst
发表时间：2019-03-10
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- 论文类型：
- 期刊论文
- 第一作者：
- Lu, Guang
- 通讯作者：
- Li, XY (reprint author), Dalian Univ Technol, Key Lab Ind Ecol & Environm Engn, Dalian 116024, Peoples R China.
- 合写作者：
- Li, Xinyong,Qu, Zhenping,Wang, Yuxin,Chen, Guohua
- 发表时间：
- 2008-12-30
- 发表刊物：
- APPLIED SURFACE SCIENCE
- 收录刊物：
- SCIE
- 文献类型：
- J
- 卷号：
- 255
- 期号：
- 5
- 页面范围：
- 3117-3120
- ISSN号：
- 0169-4332
- 关键字：
- WO3/SiO2; Commercial silica gel; Cyclopentene; Glutaraldehyde; H2O2
- 摘要：
- The WO3/SiO2 catalyst was prepared by sonication-impregnation combination approach using commercial silica gel as support. Influences of various factors on the yield of glutaraldehyde, such as WO3 loading and calcination temperature, were investigated and discussed in terms of the characterizations results of BET, XRD, Raman, FT-IR and XPS. It was found that the yield of glutaraldehyde increased rapidly with increase of WO3 loadings and calcination temperatures while WO3 was in the amorphous state, which reached the maximum value when amorphous WO3 started transforming into the crystalline form. Whereas, the yield of glutaradehyde decreased with further increase of WO3 loadings and calcination temperatures while WO3 has already transformed into the crystalline form. It is concluded that the formation of crystalline WO3 species and the interaction of WO3 with SiO2 play a key role for improving the activity of the WO3/SiO2 catalyst. (C) 2008 Elsevier B.V. All rights reserved.
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